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By the cooperative effect between photoactive azo moieties and photoinert groups, a small external stimulus can induce a large change in the refractive index of the materials, a phenomenon that has been widely used in holographic recording. This is especially useful in bulk lms of azo BCs with azo mesogens in the minority phase within glassy PMMA substrates; for instance, photoinduced mass transfer is greatly prohibited because of the microphase separation in the process of holographic recording, which led to lack of surface relief structures (Frenz et al., 2004). Thus, refractive index modulation plays an important role in the grating formation in this case. As shown in Fig. 12.20, two holographic gratings were recorded in lms of two PMMA-based azo BCs, one of which is a well-de ned azo diblock copolymer; the other sample is a diblock random copolymer. Here the diblock random copolymer is formed by two blocks. One segment is well de ned, and the other mesogenic block is statistically random. After grating formation, neither lm showed a surface relief structure, and only RIGs were obtained. Upon irradiation of two coherent laser beams, RIG in the azo diblock copolymer was recorded by alignment of the azo moieties in microphase-separated domains. In contrast, the photoinduced alignment of the azo was ampli ed by the photoinert cyanobiphenyl moieties as a result of the cooperative effect in the diblock random copolymer (Yu, et al., 2008a). This resulted in a similar refractive index modulation as in the case of the left one in Fig. 12.20, although the azo content was lower in the azo BC. The cooperative motion was con ned within the nanoscale phase domains, unlike the case of random copolymers (Wu et al., 1998).

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E (V) -3.0403 -2.98 -2.92 -2.931 -2.912 -2.89 -2.868 -2.71 -2.372 -1.847 -1.662 -0.7620 -0.447 -0.4032 -0.3384 -0.336 -0.1377 -0.1264 0.3417 0.851 0.7994

Fortunately, the high density of blade environments makes them ideal for creating failover capabilities within a single blade chassis or over a distance. Planning for failover from the very beginning is an essential part of any bestpractices list. Adding virtualization to the blade increases the business impact associated with blade failing. Instead of just one application failing, there are now multiple virtual machines and their applications failing, affecting potentially hundreds of users. Q Does your management or virtualization software include high availability (HA) clustering

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Fabrication of well-arranged metal nanoparticle arrays by using nanocylinder structured template lms is one of the important topics in nanotechnology. The size and the periodicity of the nanoparticle arrays can be controlled independently by choosing appropriate templates. This control has been achieved by using wellordered nanotemplate lms of PEO-based azo LCBCs (Li et al., 2007b). As shown in Fig. 12.21, a well-ordered array of Ag nanoparticles was fabricated successfully

Electrode OH/O 2 (g) F~/F2(g)

442 H-aggregation Dipole function Several molecules Yes No No LC and I Nanoscale Yes Phase transition Phase separation Mass transportation Whole molecule Macroscale Yes SRG I to SmX Many molecules LC: Yes I: Yes RIG

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Figure 12.20. Enhancement of surface index modulation of azo BCs by cooperative effect. A is aligned, and R is random. Source: Reproduced from Yu et al., 2008a.

cr/ci2(g)

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is given as = E + ^ l n ^ (3.2.5) zF a where a is the activity of the metal in the amalgam and a+ is the activity of its ions in the solution. Combination of two amalgam electrodes with the same activity of cations in solution and different activities of the metal in the amalgam yields a different type of concentration cell, for example K,Hg( fll ) | KCl(m) | K,Hg( 2) with RFy ax = lnF a2 If ax >a2, then short circuiting of this cell results in potassium dissolution at the left-hand electrode and incorporation into the amalgam at the righthand electrode. Amalgam electrodes can be used as reversible electrodes, even for metals as reactive as the alkali metals, especially in some non-aqueous solvents. Theoretically, the most important cationic electrode of the first kind is the hydrogen electrode. This is a gas electrode at which equilibrium is (3.2.6)

over a large area on soft or hard substrates (PET sheets, Si wafers, and quartz plates) via the selective Ag+ doping of the hydrophilic PEO domains in a microphase-separated azo LCBC lm and an associated vacuum ultraviolet UV (VUV) treatment to eliminate the LCBC templates to reduce simultaneously the Ag+. Obviously, the periodicity of the highly dense Ag nanoparticles was precisely controlled by the nanotemplates of the azo LCBC lms. The simple and facile fabrication of a metal nanoparticle array can be used as a novel type of BC photolithography to overcome the size limitations of conventional top down lithography, with the goal of macroscopically fabricating hierarchical nanopatterns with controlled ordering for potential applications ranging from photonics and plasmonics to metal wiring in molecular electronics (Suzuki et al., 2007). The self-assembly from azo LCBC lm templates also provides a good method to modify the nanoscale shape of various kinds of functional materials, such as electric conducting RuO2, magnetic Fe, or organic conducting polymers (Suzuki et al., 2007).

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